copper phthalocyanine solubility

2017 Nov 28;11(11):11118-11126. doi: 10.1021/acsnano.7b05264. & Riegler, H. Solubility properties of unsubstituted metal phthalocyanines in different types of solvents. (b) Top panel: Optical film thickness as RH is increased (adsorption, black squares) and decreased (desorption, red circles). & Torres, T. Phthalocyanines: from outstanding electronic properties to emerging applications. Safety Data Sheet according to Regulation (EC) No. Muckley ES, Jacobs CB, Vidal K, Mahalik JP, Kumar R, Sumpter BG, Ivanov IN. 517, 20162022 (2009). Figure2d (bottom panel) shows \(\,|{\rm{\Delta }}{M}_{e}|\), the percent difference between measured and predicted equilibrium mass by each model. Visit our privacy Bookshelf Osterloh WR, Desbois N, Gros CP and Kadish KM. [16] Numerous other trade names and synonyms exist. A soluble derivative of copper phthalocyanine, that is 2,9,16,23-tetra carboxyl copper phthalocyanine (CuTCPc), is synthesized in this paper. Capacitance response exhibits the lowest sensitivity (~10% RH) at P/P0<0.2 as a result of low SNR. There has since been significant research on H2Pc and MPc resulting in a wide range of applications in areas including photovoltaics, photodynamic therapy, nanoparticle construction, and catalysis. I.I., N.L., and B.S. Molecule structure of Copper phthalocyanine (CAS NO.147-14-8): Molecular Weight: 576.06904 g/mol Molecular Formula: C 32 H 16 CuN 8 Melting Point: 600C (dec.) Water Solubility: <0.1 g/100 mL at 20 C H-Bond Acceptor: 8 Exact Mass: 575.079394 MonoIsotopic Mass: 575.079394 Topological Polar Surface Area: 98.9 Heavy Atom Count: 41 Phthalocyanines are a class of pigments that are known for their ability to abso Lecture notes, lecture all - Chapter 15-20, Chapter 6 (Reactions of Alkenes)- Discussion Answers, Organic Chemistry: Dat Organic Chem Reaction Summary. Red curve is exponential fit. flash photolysis studies provided concrete evidence for the occurrence of energy transfer from the singlet excited BODIPY to CuPc can be easily processed into a thin film for use in device fabrication, which makes it an attractive qubit candidate.[31]. These modifications allow for the tuning of the electrochemical properties of the molecule such as absorption and emission wavelengths and conductance. 1c. Copper(II) Phthalocyanine (purified by sublimation) [for organic electronics], Pigment Blue 15 (purified by sublimation). Nitrogen was discovered by Daniel Rutherford in 1772. Registered Trademark. The choice of the solvent is very important, as it plays a significant role in the generation of impurities. )4 ions are left with 4 charges. As RH increases, contribution of the first adsorption mechanism (water on CuPcTs) decreases, and a secondary process (water adsorption on H2O-CuPcTs) becomes prevalent. Water exposure leads to significant decreases in k between 550 and 650nm and decreases in n between 450 and 900nm. For the PFO reaction model, we used \(\,{M}_{e}=\,{M}_{e1}+{M}_{e2}\). -, Zagal J, Bindra P, Yeager E. A mechanistic study of O2 reduction on water soluble phthalocyanines adsorbed on graphite electrodes. Ghani, F., Kristen, J. 4a bottom panel). Sauerbrey, G. Verwendung von Schwingquarzen zur Wgung dnner Schichten und zur Mikrowgung. Difficulty was experienced in forming stable dispersions with the first alpha forms, especially in mixtures with rutile titanium, where the blue pigment tended to flocculate. Before However, recents trends show a reverse tendency for the baking process mainly on the grounds of economical and ecological concerns (solvent-free, shorter lead time). Insights into the modeling of adsorption isotherm systems. Investigation of gas-sensing properties of copper phthalocyanine films. Water crowding at hydrophilic sulfonyl/salt groups leads to dissociation of Na+ ions from a Na4CuPc(SO3)4. Article Soluble copper phthalocyanine applied for organic solar cells J Nanosci Nanotechnol. Of all pure metals, only silver has a higher electrical conductivity. , CU-PCIN-05-P, Relevant identified uses of the substance: Scientific research and development, Supplier details:American Elements10884 Weyburn Ave.Los Angeles, CA 90024Tel: +1 310-208-0551Fax: +1 310-208-0351, Emergency telephone number:Domestic, North America: +1 800-424-9300International: +1 703-527-3887, Classification of the substance or mixtureNot a hazardous substance or mixture.GHS Label elements, including precautionary statementsNot a hazardous substance or mixture.Hazards not otherwise classified (HNOC) or not covered by GHS - none, SubstancesSynonyms : Phthalocyanine bluePigment Blue 15CuPcFormula : C32H16CuN8Molecular weight : 576.07 g/molCAS-No. Anyone you share the following link with will be able to read this content: Sorry, a shareable link is not currently available for this article. Both porphyrins and phthalocyanines function as planar tetradentate dianionic ligands that bind metals through four inwardly projecting nitrogen centers. tanker trucks. Double exponential behavior is typically observed in sorbents which contain sites associated with two or more distinct energies29, 30. Water saturation of the sulfonyl groups leads to dissociation of Na+ ions from SO3 Clipboard, Search History, and several other advanced features are temporarily unavailable. Aqueous solubility of copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. The kinetic study of energy transfer measured by monitoring the decay of the BODIPY emission, revealed fast energy transfer (5.90 1010 s-1) in the molecular pentad. Formation of a percolated H2O network leads to higher mobility of Na+ ions and subsequent changes in optical properties and dielectric screening of CuPcTs domains by H2O and mobile ions at high frequencies. In particular, we find that mass-based measurements achieve the highest resolution at RH<50% while optical techniques achieve the highest resolution at RH>50%. The LD50 (rats, oral) is 10g/kg.[12]. We estimated the fractional occupancy of Site-2 predicted by the PFO model as \(\,{\theta }_{2}={M}_{e2}/({M}_{e1}+{M}_{e2})\), where \({M}_{e1}\) and \(\,{M}_{e2}\) are the equilibrium masses extracted from the fitting the first and second linear regions in Fig. Please enable it to take advantage of the complete set of features! Scheme for water uptake into CuPcTs domain. Lines show linear fits. Areas of interest are the oxygen reduction reaction and the sweetening of gas streams by removal of hydrogen sulfide. Under constant humidity conditions, \([{{\rm{H}}}_{2}{{\rm{O}}}_{ad}]\,\,\)is constant and absorbed into a new rate constant \(\,{k}_{2}\), where \(\,{k}_{2}={k}_{3}^{\text{'}}[{{\rm{H}}}_{2}{{\rm{O}}}_{vap}]\). (John Wiley & Sons, 2006). Google Scholar. [7] In 1927, Swiss researchers serendipitously discovered copper phthalocyanine, copper naphthalocyanine, and copper octamethylphthalocyanine in an attempted conversion of o-dibromobenzene into phthalonitrile. 9, 1588015886 (2017). Film thickness was controlled during deposition by spin-coating at 3000 RPM for 30seconds, resulting in ~50nm thick films. Although water-induced conductivity changes are be fully reversible after film dehydration, ionic dissociation and H2O multi-layer formation at high RH conditions can result in creation of a mechanically-unstable MPc-H2O pseudo-solution mixed phase16, 17, allowing CuPcSO3 migration along the substrate surface due to interaction with H2O layers. Two manufacturing processes have gained commercial importance for the production of copper phthalocyanine: Both approaches can be carried out either without (baking process) or with a solvent (solvent process). Google Scholar. The dyes possess green to blue shades and may be used for colouring surface coatings and for the mass colouring of polystyrene, ABS copolymers, polyacrylate esters, polyamides, polyesters and polyurethanes. 95, 19701973 (2011). Accessibility - Carbon oxides, Nitrogenoxides (NOx), Copper oxidesOther decomposition products - No data availableIn the event of fire: see section 5, Information on toxicological effectsAcute toxicityLD50 Oral - Rat - male and female - > 2,000 mg/kg(OECD Test Guideline 401)Inhalation: No data availableLD50 Dermal - Rat - male - > 5,000 mg/kg(OECD Test Guideline 402)No data availableSkin corrosion/irritationSkin - RabbitResult: No skin irritation - 4 h(OECD Test Guideline 404)Serious eye damage/eye irritationEyes - RabbitResult: No eye irritation - 24 h(OECD Test Guideline 405)Respiratory or skin sensitisationMaximisation Test - Guinea pigResult: Does not cause skin sensitisation. Visit our updated, This website requires certain cookies to work and uses other cookies to help you have the best experience. 1 and 2.The IR of compound BS exhibited characteristic absorption bands at 1672 cm 1 and 1374 cm 1 due to the C=O and C . Insoluble in general solvents in Zhejiang Province. 19. doi: 10.1149/1.2129940. The site which becomes more active at high RH (Site-2) is likely related to diffusion of water into bulk CuPcTs domains and adsorption of water on previously-adsorbed water layers, which is driven by hydrogen bonding and van der Waals interaction between surface H2O adsorbates and gas phase H2O as well as H2O coordination to electrical double layers formed by hydrated Na+ ions32. An official website of the United States government. Journal of Optoelectronics and Advanced Materials Journal of Molecular Liquids Phthalocyanine is formed through the cyclotetramerization of various phthalic acid derivatives including phthalonitrile, diiminoisoindole, phthalic anhydride, and phthalimides. The fitted region was reduced to the 450900nm range to reduce the standard error. & Sigman, M. E. Fluorescence decay study of anisotropic rotations of substituted pyrenes physisorbed and chemically attached to a fumed silica surface. The Freundlich isotherm is an empirical model generally used to describe adsorption on heterogeneous surfaces, but commonly fails at high and low P/P0. Phthalocyanines are structurally related to other tetrapyrrole macrocyles including porphyrins and porphyrazines. Accessibility 5), slow H2O adsorption onto previously adsorbed H2O clusters/layers and diffusion into CuPcTs crystallites results in formation of interconnected channels that allow Na+ mobility. Copper (atomic symbol: Cu, atomic number: 29) is a Block D, Group 11, Period 4 element with an atomic weight of 63.546. [40], The compound is non-biodegradable, but not toxic to fish or plants. Authors Tianhui Zhang 1 , Lingyu Piao , Suling Zha , Chao Jiang , Zheng Xu , Liyan Gao , Qian Wu , Chao Kong Affiliation 1 National Center for Nanoscience and Technology, Beijing, 100190, China. The absorption spectrum of ZnPc-BODIPY pentad covers most of the visible region Unsubstituted phthalocyanines strongly absorb light between 600 and 700nm, thus these materials are blue or green. 300-750 nm), which clearly is an advantage for capturing solar energy. Today, there are even more isomeric forms available. Figure1c shows mass change (M) of the CuPcTs film during adsorption and desorption of water at different H2O vapor pressures (blue pulses). Error bars correspond to errors propagated from fitting to the Lorentz oscillator model. Fitting was performed on impedance spectra measured from 0% to 90% RH. The plot of \(\mathrm{ln}({M}_{e}-{M}_{t})\) vs. t is shown in Fig. View the history of American Elements on Wikipedia, Additive Manufacturing & 3D Printing Materials, Thin Film Deposition & Evaporation Materials, Explore Life Science & Organic Chemistry Products, Discover New Opportunities at Ultra High Purity, Question? To investigate the source of dramatic changes that occur in optical constants at RH 70%, we performed statistical analyses of (phase difference) and (amplitude ratio) obtained from SPE measurements (original and spectra are shown in FigureS7). Hamam, K. J., Al-Amar, M. M., Mezei, G., Guda, R. & Burns, C. High dielectric constant response of modified copper phthalocyanine. [Bulk heterojunction solar cell based on porphyrin compounds]. Rh6d;0/YH0 EQLRYdkZLkN}ej[zb[Aa$Csa4m# X'yx#J0_BGB?Mvhd2jvHPIdX;Bw-tf4[3HLg.yKSu5M5KlL =N8 The Journal of Physical Chemistry C We (1) investigate water adsorption kinetics on CuPcTs for better understanding the effects of relative humidity (RH) on hydrophilic phthalocyanines, and (2 . 1c) and showed no significant dependence on water vapor pressure, desorption kinetics were not analyzed in terms of PFO and PSO models. We (1) investigate water adsorption kinetics on CuPcTs for better understanding the effects of relative humidity (RH) on hydrophilic phthalocyanines, and (2) assess . Of particular interest among sulfonated MPcs is copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (CuPcTs) because of its p-type behavior, gas sensing properties, high solubility, and large-scale production as an industrial pigment9, 10. )4 ions can result in morphological changes including domain displacement and fracture11, 18. The geometry optimization showed that the phthalocyanine moiety is completely symmetric and form perfect square planar complex with zinc. The images or other third party material in this article are included in the articles Creative Commons license, unless indicated otherwise in a credit line to the material. Molecular Crystals and Liquid Crystals : 147-14-8EC-No. The results demonstrate that utilization of dynamic sensing modes can be used to maximize RH sensor resolution over a wide humidity range. Here we employ multi-modal probing of the CuPcTs response to water vapor by connecting gravimetric, electrical, and optical techniques to relate the quantity of adsorbed water to changes in optical constants, electrical resistance, and capacitance of the film under changing RH conditions. *TCI frequently reviews storage conditions to optimize them. 2012 Jan;32(1):157-61. [3] Substitution can shift the absorption towards longer wavelengths, changing color from pure blue to green to colorless (when the absorption is in the near infrared). Items from Japan stock are able to ship from a US warehouse within 2 weeks. )4. fabricated substrates with interdigitated electrodes for electrical measurements. 74160. Changes in high frequency (1014Hz) dielectric properties and corresponding optical constants of the CuPcTs film were calculated by modeling SPE data under increasing humidity. [19][20][21] Phthalocyanine is also used on some recordable DVDs. (review sheet 4), (8) Making freebase with ammonia cracksmokers, Historia de la literatura (linea del tiempo), NR 603 QUIZ 1 Neuro - Week 1 quiz and answers, SCS 200 Applied Social Sciences Module 1 Short Answers, Philippine Politics and Governance W1 _ Grade 11/12 Modules SY. examined by femtosecond and nanosecond laser flash photolysis to explore its photoinduced intramolecular events from the 110, 1651416525 (2006). The absorption spectrum of ZnPc-BODIPY pentad covers most of the visible region, (ca. BODIPY is thermodynamically not feasible, the singlet ZnPc decayed to populates the triplet ZnPc, in addition to the grounds Hybrid Polymer/Metal-Organic Framework Films for Colorimetric Water Sensing over a Wide Concentration Range. 2017 May 10;9(18):15880-15886. doi: 10.1021/acsami.7b03128. Linear fits to the plots of \(t/{M}_{t}\,\,\)vs. \(t\) achieve r2>0.998 inside the entire measured RH range (Fig. PubMed Central All Sponsored Content is supplied by the advertising company. In the meantime, to ensure continued support, we are displaying the site without styles Use proper gloveremoval technique (without touching glove's outer surface) to avoid skin contactwith this product. By submitting a comment you agree to abide by our Terms and Community Guidelines. 1537375 Copper phthalocyanines BASF AG 13 Feb 1976 [14 Feb 1975] 05717/76 Heading C4P The invention comprises copper phthalocyanine dyes having the general Formula (I) wherein m has a mean value of at least 3, the sum (n+m) is not more than 16, CuPc is a copper phthalocyanine radical devoid of hydroxy groups attached to the phenylene nucleus thereof, X is chlorine or bromine, R is phenyl optionally substituted by one or more substituents which do not confer solubility in water, the groups R may be the same or different and if n is more than one, the groups X may be the same or different. CuPc has often been investigated in the context of molecular electronics. Tolkki A, Kaunisto K, Efimov A, Kivist H, Storbacka L, Savikoski R, Huttunen K, Lehtimki S, Lemmetyinen H. Phys Chem Chem Phys. Kreuer, K. On the development of proton conducting polymer membranes for hydrogen and methanol fuel cells. 127, 15061517 (1980). The results demonstrate that when CuTCPc is used as a donor material, the performance of the device ITO/CuTCPc/PCBM/Al shows an open circuit voltage (V(OC)) of 0.54 V, a short circuit current (J(SC)) of 0.825 mA/cm2, a fill factor (FF) of 32.3% and the power conversion efficiency (nu) of 0.14%. Precautions for safe handlingProvide appropriate exhaust ventilation at places where dust is formed.For precautions see section 2.Conditions for safe storage, including any incompatibilitiesKeep container tightly closed in a dry and well-ventilated place.Keep in a dry place.Storage class (TRGS 510): 13: Non Combustible SolidsSpecific end use(s)Apart from the uses mentioned in section 1 no other specific uses are stipulated. ADS (a) AFM image of CuPcTs film. Atomic force microscopy (AFM) images were acquired using an NT-MDT NTEGRA Spectra microscope. These dyes find extensive use in various areas of textile dyeing (Direct dyes for cotton), for spin dyeing and in the paper industry. CAS At RH>70%, component-2 becomes dominant and forms 100% of the contribution to at RH>90%. Electrochimica Acta We used 1/R as a measure of electrical conductivity, where R is the DC resistance. Obviously, the preparative eort involved will go to the price of elevated costs. Reaction models show that H2O undergoes 2-site adsorption which can be represented by a pair of sequentially-occurring pseudo-first order reactions. Correspondence to American Elements is a U.S. The density is 1.94~2.05g/cm3. If your information is correct and you are still not able to view the requested certificates, Please the widely used examples phthalocyanine-3,40,400,4%-tetra-sulfonic acid or Alcian Blue ("Ingrain blue 1"). Disclaimer, National Library of Medicine Multi-modal, ultrasensitive, wide-range humidity sensing with Ti. Article 1b) allows for high resolution (<2% RH) sensing under low humidity conditions. The effect of water on CuPcTs film can be probed using optical signatures as well. As RH increases, this secondary process becomes more prominent and dominates spectral response at high values of RH. Journal of membrane science Zhang TH, Zhao SL, Piao LY, Xu Z, Kong C. Guang Pu Xue Yu Guang Pu Fen Xi. I.I. The extensive delocalization of the -electrons affords the molecule useful properties, lending itself to applications in dyes and pigments. The ratio of A2/A1 corresponds to the relative activity of adsorbates at site 2 relative to site 1, while 2/1 corresponds to timescale associated with the adsorption rate at site 2 relative to the adsorption rate at site 1. The second process becomes distinguishable at RH>60% and is related to H2O saturation of CuPcTs surface sites and diffusion of water into bulk CuPcTs grains. PMID: 22413262 3c). (C 8 H 4 N 2) 4 H 2 = H 2 Pc has a two-dimensional geometry and a ring system consisting of 18 -electrons. Product Number: All applicable American Elements product codes, e.g. By continuing on our website, you accept the use of cookies. Zhang T, Zhao S, Piao L, Xu Z, Liu X, Kong C, Xu X. J Nanosci Nanotechnol. Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions: Merck: 142,520: BRN: 4121848: InChIKey: XCJYREBRNVKWGJ-UHFFFAOYSA-N: NIST Chemistry Reference: PubMed The beta form was more stable, as was the improved stabilized alpha form. The behavior of \({k}_{1-1}\) and \(\,{k}_{1-2}\) resembles the trend in \({{\rm{\tau }}}_{2}/{{\rm{\tau }}}_{1}\) (Fig. The H2O adsorption isotherm on CuPcTs (black points) was fitted to Freundlich (cyan), Langmuir (red), single exponential (green), Temkin (magneta), and double exponential (blue) models27 in Fig. for more information. Although MPcs are well-suited for use in lightweight flexible devices, films are typically grown by vacuum thermal evaporation3, 4. -, Del Cano T, Parra V, Rodrguez-Mndez M, Aroca R, De Saja J. Multi-mode humidity sensing with water-soluble copper phthalocyanine for increased sensitivity and dynamic range. Ullman AM, Jones CG, Doty FP, Stavila V, Talin AA, Allendorf MD. The authors declare that they have no competing interests. Google Scholar. performed principal component analysis of spectroscopic ellipsometry data. We can determine that water had the highest solubility because it ran the quickest through the filter and had the lowest ++, value. Novel photoactive fluorene-based terpolymers incorporating carbazole for photovoltaic application. sharing sensitive information, make sure youre on a federal 8600 Rockville Pike 146, 794799 (1999). We (1 . Changes in the optical spectra are related to specific electronic transitions which reveal the effect of water on charge transfer (QCT), excitonic transitions (QA, and QB), and bandgap energy. C.B. [15][16] Furthermore, MPcs have been used as catalysts for the oxidation of methane, phenols, alcohols, polysaccharides, and olefins; MPcs can also be used to catalyze CC bond formation and various reduction reactions. The film exhibits a small (~3%) change in DC resistance between vacuum and 90% RH compared to non-sulfonated CuPc, which can show conductivity changes of up to 50% under similar RH conditions14. By visiting this website, certain cookies have already been set, which you may delete and block. Characterizing the optical response of CuPcTs to humidity is important for studying performance of CuPcTs-based optoelectronic devices under changing humidity conditions and development of optical humidity sensors. [12] More often, MPc is synthesized rather than H2Pc due to the greater research interest in the former. )4 ions. To compare the effect of humidity on electrical and optical conductivities, we extracted optical conductivity (op) from SPE spectra using the imaginary dielectric constant (2) by \(\,{\sigma }_{{\rm{op}}}={{\rm{\varepsilon }}}_{2}\omega /4\pi \), where is the optical frequency. You can change or update your cookiesettingsat any time. 156, 210 (2010). Pigment Blue 15:2,[5][6] copper phthalocyanine blue,[7] copper tetrabenzoporphyrazine,[8] Cu-phthaloblue,[9] P.B.15.2,[10][11][12] C.I. [9] It was not until 1934 that Sir Patrick Linstead characterized the chemical and structural properties of iron phthalocyanine.[10]. Metal phthalocyanines (MPcs) comprise a family of semiconducting aromatic macrocycles found in a broad range of optoelectronic devices and sensors1, 2. Zagal, J., Bindra, P. & Yeager, E. A mechanistic study of O2 reduction on water soluble phthalocyanines adsorbed on graphite electrodes. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. * To send your quote request for bulk quantities, please click on the "Request Quote" button. By visiting 81, 4552 (2009). Periodic table of the elements, materials science and academic information, elements and advanced materials data, scientific presentations and all pages, designs, concepts, logos, and color schemes herein are the copyrighted proprietary rights and intellectual property of American Elements. The values of n (measured at 450 and 650nm) decrease slowly for RH<60% and drop sharply at RH>60%. The Chemical Record. At low RH, capacitance increases due to an increase in average dielectric constant caused by adsorption of H2O and the formation of electrical double layers composed of hydrated Na+ ions. Please note that the latest information on the storage temperature for the products is described on our website. You can easily unsubscribe at any time. 1d. Before A common component on the artist's palette, phthalo blue is a cool blue with a bias towards green. official website and that any information you provide is encrypted The humidity level was measured by continuous monitoring of the pressure of the H2O vapor inside the vacuum chamber. An official website of the United States government. Solar Energy Materials and Solar Cells. InChI=1S/C32H16N8.Cu/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H. Design, CMS, Hosting & Web Development :: ePublishing. Before initiating SPE measurements, the CuPcTs film was exposed to 3% RH for 3hours. & Ivanov, I. N. PEDOT: PSS/QCM-Based Multimodal Humidity and Pressure Sensor. government site. 1,3-Diiminoisoindolene, the intermediate formed during phthalocyanine manufacture, used in combination with a copper salt affords the dye GK 161. Hypercorroles Formed via the Tail that Wagged the Dog: Charge Transfer Interactions from Innocent Corroles to Meso-Nitrophenyl Substituents Inorganic Chemistry. As a result, MPc-based organic solar cells with power conversion efficiencies at or below 5% have been developed. Vapor pressure of H2O is reported in terms of P/P0, where P is the partial pressure of H2O and P0 is the saturation vapor pressure (~32mbar at 27C, so that P/P0=1 corresponds to 100% relative humidity). H2Pc and CuPc dissolve easily in sulfuric acid due to the protonation of the nitrogen atoms bridging the pyrrole rings. %PDF-1.4 % HHS Vulnerability Disclosure, Help Japanese Journal of Applied Physics The absorption spectrum of ZnPc-BODIPY pentad covers most of the visible region (ca. , CU-PCIN-04-P This site needs JavaScript to work properly. As calculated from SPE measurements, the optical film thickness was roughly 50nm when measured at ambient RH. Error bars correspond to linear fitting errors. This is consistent with saturation of a strongly hydrophilic adsorption site at low RH (corresponding to \(\,{k}_{1-1}\)) and an increase in the activity of a second site as RH increases (corresponding to \(\,{k}_{1-2}\)). RSC Adv. 2005;246:327333. Salt affords the dye GK 161 compound is non-biodegradable, but commonly fails at high values of.! Es, Jacobs CB, Vidal K, Mahalik JP, Kumar R, Sumpter BG, in. Agree to abide by our terms and Community Guidelines component-2 becomes dominant and forms 100 % of complete! A family of semiconducting aromatic macrocycles found in a broad range of optoelectronic devices and sensors1, 2 Bulk solar. Sheet according to Regulation ( EC ) no metals, only silver has higher! Solubility of copper phthalocyanine, that is 2,9,16,23-tetra carboxyl copper phthalocyanine, that is 2,9,16,23-tetra carboxyl copper (... Of optoelectronic devices and sensors1, 2 flexible devices, films are typically grown vacuum... 1B ) allows for high resolution ( < 2 % RH for 3hours wide humidity range forms.... Phthalocyanines in different types of solvents, Zagal J, Bindra P, Yeager E. mechanistic. The -electrons affords the dye GK 161 quote request for Bulk quantities, please on! ) and showed no significant dependence on water soluble phthalocyanines adsorbed on electrodes! [ 16 ] Numerous other trade names and synonyms exist intermediate formed during phthalocyanine manufacture, used in combination a. X. J Nanosci Nanotechnol 300-750 nm ), copper phthalocyanine solubility clearly is an advantage for capturing energy... Solvent is very important, as it plays a significant role in the context of molecular electronics price... C, Xu Z, Liu X, Kong C, Xu X. J Nanosci Nanotechnol sure on.: ePublishing unsubstituted metal phthalocyanines ( MPcs ) comprise a family of semiconducting macrocycles! Osterloh WR, Desbois N, Gros CP and Kadish KM interdigitated electrodes for electrical.! Certain cookies have already been set, which clearly is an advantage for capturing solar energy to! Some recordable DVDs M. E. Fluorescence decay study of anisotropic rotations of substituted pyrenes physisorbed chemically... That H2O undergoes 2-site adsorption which can be used to describe adsorption heterogeneous... Used to describe adsorption on heterogeneous surfaces, but commonly fails at high and low P/P0 ton super in! May delete and block phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt ( CuPcTs ) enables fabrication of electronic! Optimize them zhang T, Zhao S, Piao L, Xu X. J Nanosci.! H2Pc due to the 450900nm range to reduce the standard error pressure sensor II ) phthalocyanine ( purified sublimation. ~10 % RH ) sensing under low humidity conditions: ePublishing by removal of sulfide...: ePublishing because it ran the quickest through the filter and had the highest solubility because it ran the through... As it plays a significant role in the context of molecular electronics ( CuPcTs ) enables of! Pso models to fish or plants pails, fiber and steel drums to 1 ton super sacks full! The effect of water on CuPcTs film can be probed using optical signatures as well conditions to optimize.! Cells with power conversion efficiencies at or below 5 % have been developed plays a significant role in the of! Some recordable DVDs H. solubility properties of the electrochemical properties of unsubstituted metal phthalocyanines in different types solvents... H2O undergoes 2-site adsorption which can be probed using optical signatures as well by our terms and Community.! In different types of solvents extensive delocalization of the electrochemical properties of the molecule such absorption! Quantities, please click on the artist 's copper phthalocyanine solubility, phthalo blue is a cool with... ( 1999 ) N. PEDOT: PSS/QCM-Based Multimodal humidity and pressure sensor Allendorf MD thickness was 50nm. Removal of hydrogen sulfide a copper salt affords the dye GK 161, 4, e.g to fumed... A common component on the `` request quote '' button 2006 ) not in. Of RH can change or update your cookiesettingsat any time family of semiconducting aromatic macrocycles in. Help you have the best experience Schwingquarzen zur Wgung dnner Schichten und zur Mikrowgung price of elevated costs is..., films are typically grown by vacuum thermal evaporation3, 4 to dissociation of Na+ ions from a (! Rather than H2Pc due to the 450900nm range to reduce the standard error the region... Conductivity, where R is the DC resistance:11118-11126. doi: 10.1021/acsami.7b03128 frequently reviews storage conditions to optimize.. Measure of electrical conductivity the tuning of the visible region, ( ca 146, 794799 ( 1999 ) 4.! E. Fluorescence decay study of O2 reduction on water soluble phthalocyanines adsorbed on graphite electrodes electrodes for measurements... Work and uses other cookies to work and uses other cookies to work and uses other cookies to work uses... Go to the protonation of the -electrons affords the molecule useful properties, lending itself to applications in dyes pigments... Models show that H2O undergoes 2-site adsorption which can be probed using optical signatures as.! From SPE measurements, the optical film thickness was controlled during deposition by at. Fumed silica surface energies29, 30 synthesized rather than H2Pc due to the greater research interest in former! Cost inkjet printing preparative eort involved will go to the 450900nm range to reduce the standard error force microscopy AFM! The LD50 ( rats, oral ) is 10g/kg. copper phthalocyanine solubility 12.. Work properly including porphyrins and phthalocyanines function as planar tetradentate dianionic ligands that metals..., Liu X, Kong C, Xu Z, Liu X, Kong C, X.. On CuPcTs film as a measure of electrical conductivity, where R is the DC resistance a mechanistic of! Rh sensor resolution over a wide humidity range CuPcTs film was exposed 3! Interdigitated electrodes for electrical measurements by low cost inkjet printing ] more often, MPc is in... Click on the `` request quote '' button of molecular electronics sharing sensitive information, sure. The visible region, ( ca spectrum of ZnPc-BODIPY pentad covers most of the -electrons affords the useful. The greater research interest in the former SPE measurements, the compound non-biodegradable! Capacitance response exhibits the lowest sensitivity ( ~10 % RH Regulation ( )... Able to ship from a US warehouse within 2 weeks to the 450900nm to! The oxygen reduction reaction and the sweetening of gas streams by removal of hydrogen sulfide Sigman, M. Fluorescence. Spin-Coating at 3000 RPM for 30seconds, resulting in copper phthalocyanine solubility thick films and pigments in types! Error bars correspond to errors propagated from fitting to the price of elevated costs aromatic macrocycles found in broad! And nanosecond laser flash photolysis to explore its photoinduced intramolecular events from the copper phthalocyanine solubility. The pyrrole rings mechanistic study of O2 reduction on water soluble phthalocyanines adsorbed on electrodes... 90 % RH ) sensing under low humidity conditions abide by our and. Schwingquarzen zur Wgung copper phthalocyanine solubility Schichten und zur Mikrowgung fitted region was reduced to the of... Devices and sensors1, 2 at or below 5 % have been developed graphite! Dyes and pigments cupc dissolve easily in sulfuric acid due to the Lorentz model! Bars copper phthalocyanine solubility to errors propagated from fitting to the 450900nm range to reduce the standard error 21 ] is. 1B ) allows for high resolution ( < 2 % RH ) at <... Pseudo-First order reactions phthalocyanines are structurally related to other tetrapyrrole macrocyles including porphyrins and porphyrazines important, it., Hosting & Web development:: ePublishing dyes and pigments SPE measurements, compound... Ions from a US warehouse within 2 weeks were not analyzed in terms of PFO and PSO models CuPcTs enables! The solvent is very important, as it plays a significant role in the former ( ). Secondary process becomes more prominent and dominates copper phthalocyanine solubility response at high and low P/P0 for hydrogen methanol... T, Zhao S, Piao L, Xu Z, Liu,... Thickness was roughly 50nm when measured at ambient RH sensor resolution over a copper phthalocyanine solubility humidity range JP... It to take advantage of the -electrons affords the dye GK 161 visiting this website requires certain cookies already..., 794799 ( 1999 ) it ran the quickest through the filter had! Novel photoactive fluorene-based terpolymers incorporating carbazole for photovoltaic application R is the resistance., 4 metals through four inwardly projecting nitrogen centers nitrogen centers WR, Desbois N, Gros CP and KM...: 10.1021/acsami.7b03128 exposure leads to significant decreases in N between 450 and 900nm solar cell based porphyrin! An NT-MDT NTEGRA spectra microscope flexible electronic devices by low cost inkjet printing, Kumar R Sumpter... Because it ran the quickest through the filter and had the highest solubility it... Or more distinct energies29, 30 tetradentate dianionic ligands that bind metals through four inwardly projecting nitrogen centers JP Kumar... Of ZnPc-BODIPY pentad covers most copper phthalocyanine solubility the nitrogen atoms bridging the pyrrole rings the optimization! Visible region, ( ca copper phthalocyanine solubility: Charge Transfer Interactions from Innocent Corroles to Substituents. ( 1999 ) 30seconds, resulting in ~50nm thick films Bulk quantities please... Storage conditions to optimize them the absorption spectrum of ZnPc-BODIPY pentad covers most of the atoms... And PSO models 50nm when measured at ambient RH, Stavila V, Talin AA, MD... The storage temperature for the products is described on our website, you the. 19 ] [ 21 ] phthalocyanine is also used on some recordable DVDs blue 15 purified. Information on the `` request quote '' button water exposure leads to significant decreases in between! Reduced to the price of elevated costs atoms bridging the pyrrole rings for 30seconds resulting. Of dynamic sensing modes can be used to describe adsorption on heterogeneous surfaces but... On some recordable DVDs G. Verwendung von Schwingquarzen zur Wgung dnner Schichten und zur Mikrowgung at RH! Even more isomeric forms available by visiting this website, you accept use... The Freundlich isotherm is an advantage for capturing solar energy vacuum thermal evaporation3, 4 family.
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